Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/10077
Title: Polymeric thermal analysis of C+H and C+H+Ar ion implanted UHMWPE samples
Authors: Kaya, N.
Öztarhan, Ahmet M.
Urkaç, Emel Sokullu
Ila, D.
Budak, S.
Oks, E.
Tıhmınlıoğlu, Funda
Muntele, C.
Keywords: Heat capacity
Melting temperature
Cross-linking
Melting enthalpy
Branch
Glassy transition temperature
Publisher: Elsevier Ltd.
Abstract: Chemical surface characterization of C + H hybrid ion implanted UHMWPE samples were carried out using DSC (differential scanning calorimeter) and TGA (thermal gravimetric analysis) techniques. Samples were implanted with a fluence of 10(17) ion/cm(2) and an extraction voltage of 30 kV. The study of TGA and DSC curves showed that: (1) Polymeric decomposition temperature increased, (2) T-m, Delta C-p and Delta H-m values changed while Delta C-p and Delta H-m increased. T-g value could not be measured, because of some experimental limitations. However, the increase in Delta H-m values showed that T-g values increased, (3) the branch density which indicated the increase in number of cross-link (M-c) decreased in ion implanted samples and (4) increase in Delta H-m values indicated increase in crystallinity of implanted surface of UHMWPE samples.
Description: 19th International Conference on Application of Accelerators in Research and Industry
URI: https://doi.org/10.1016/j.nimb.2007.04.098
https://hdl.handle.net/10077
ISSN: 0168-583X
Appears in Collections:Chemical Engineering / Kimya Mühendisliği
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

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