Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/10401
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dc.contributor.authorOrak, Ceren-
dc.contributor.authorYüksel Özşen, Aslı-
dc.date.accessioned2021-01-24T18:34:36Z-
dc.date.available2021-01-24T18:34:36Z-
dc.date.issued2020-
dc.identifier.issn0888-5885-
dc.identifier.urihttps://doi.org/10.1021/acs.iecr.0c02562-
dc.identifier.urihttps://hdl.handle.net/10401-
dc.description.abstractThe nitrogen-containing heterocyclic organic compound, 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU), was chosen to prepare a model solution to represent nitrogen-containing industrial waste streams. A hybrid reactor system was designed to combine electrolysis with wet oxidation in hot compressed water using a titanium electrode. The effects of current density, NaOH concentration, and reaction time on DBU and total organic carbon (TOC) removal were investigated via Minitab 18 software to clarify the main and interaction effects. Statistical analysis shows that the NaOH concentration and current density had significant effects on DBU removal. The highest DBU (91.2%) and TOC (45%) removal was observed at the lowest DBU concentration (3 mM) for 90 min of reaction time. Last, the effect of temperature on DBU and TOC removal was investigated. TOC removal was described with the first-order reaction kinetic model. Rate constants were determined as 0.0025, 0.041, and 0.050 min(-1) at 200, 240, and 280 degrees C, respectively. The activation energy was calculated as 79.86 kJ/mol.en_US
dc.description.sponsorshipThis research was financially supported by a Marie Curie Career Integration Grant (FP7-PEOPLE-2012-CIG) with a project number PCIG11-GA-2012-321741. We would like to thank Orkan Dal and Emre Demirkaya for their help in some experiments. We would also like to thank "Environmental Reference Research and Development Center" at the Izmir Institute of Technology for their support in product analysis.en_US
dc.language.isoenen_US
dc.publisherAmerican Chemical Societyen_US
dc.relation.ispartofIndustrial and Engineering Chemistry Researchen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.titleElectrolytic oxidation of 1,8-diazabicyclo[5.4.0]undec-7-ene in hot-compressed water on a titanium electrodeen_US
dc.typeArticleen_US
dc.institutionauthorOrak, Ceren-
dc.institutionauthorYüksel Özşen, Aslı-
dc.departmentİzmir Institute of Technology. Chemical Engineeringen_US
dc.identifier.volume59en_US
dc.identifier.issue43en_US
dc.identifier.startpage19153en_US
dc.identifier.endpage19161en_US
dc.identifier.wosWOS:000586870700008en_US
dc.identifier.scopus2-s2.0-85096054872en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.identifier.doi10.1021/acs.iecr.0c02562-
dc.relation.doi10.1021/acs.iecr.0c02562en_US
dc.coverage.doi10.1021/acs.iecr.0c02562en_US
local.message.claim2022-09-05T10:05:31.163+0300|||rp02519|||submit_approve|||dc_contributor_author|||None*
dc.identifier.wosqualityQ2-
dc.identifier.scopusqualityQ1-
item.openairetypeArticle-
item.cerifentitytypePublications-
item.languageiso639-1en-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.fulltextWith Fulltext-
item.grantfulltextopen-
crisitem.author.dept01. Izmir Institute of Technology-
crisitem.author.dept03.02. Department of Chemical Engineering-
Appears in Collections:Chemical Engineering / Kimya Mühendisliği
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
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