Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/11345
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dc.contributor.authorRecepoğlu, Yaşar Kemal-
dc.contributor.authorYüksel, Aslı-
dc.date.accessioned2021-11-06T09:46:57Z-
dc.date.available2021-11-06T09:46:57Z-
dc.date.issued2021-
dc.identifier.issn0969-0239-
dc.identifier.issn1572-882X-
dc.identifier.urihttps://doi.org/10.1007/s10570-021-04148-3-
dc.identifier.urihttps://hdl.handle.net/11147/11345-
dc.description.abstractHazelnut shell waste was phosphorylated to develop a novel biosorbent based on natural renewable resource for the recovery of lithium from aqueous solution. For the synthesized biosorbent, the surface morphology and mapping by SEM-EDS, chemical properties by FTIR, elemental analysis by XPS, specific surface area by BET, crystallinity by XRD and thermal properties by TGA were elucidated elaborately. The influence of biosorbent dosage, initial concentration, temperature, contact time, pH and coexisting ions were investigated. The equilibrium sorption capacity reached 6.03 mg/g under optimal conditions (i.e., biosorbent dosage of 12.0 g/L, initial Li concentration of 100 mg/L, pH value of 5.8, sorption temperature of 25 degrees C, and sorption time of 6 min). According to the sorption behavior of the phosphorylated hazelnut shell waste the Freundlich model proved to be more suitable than the Langmuir model indicating maximum sorption capacity as 7.71 mg/g at 25 degrees C. Thermodynamic parameters obtained by different isokinetic temperatures disclosed that the ion exchange reaction was feasible, spontaneous, and exothermic where the interaction between biosorbent surface and solvent plays an important role. A preliminary test on the Li recovery from geothermal water was also performed to check its applicability in a real brine. Desorption studies at 25 degrees C revealed that relatively higher desorption efficiency and capacity were achieved at 97.4% and 5.93 mg/g, respectively with a 1.0 M H2SO4 among other regenerants (i.e., HCl and NaCl). Concentrations of Li and the other cations were determined via ICP-OES. Due to such outstanding features, the novel phosphorylated hazelnut shell waste had great potential for lithium recovery from aqueous solution by being added value as a waste and recovering a strategic element of modern life simultaneously. [GRAPHICS] .en_US
dc.description.sponsorshipThis study was financially supported through the project of The Scientific and Technological Research Council of Turkey-TUBITAK (Project No. 219M219).en_US
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofCelluloseen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectBiomassen_US
dc.subjectBiosorbenten_US
dc.subjectHazelnut shellen_US
dc.subjectLithiumen_US
dc.subjectPhosphorylationen_US
dc.titlePhosphorylated hazelnut shell waste for sustainable lithium recovery application as biosorbenten_US
dc.typeArticleen_US
dc.authorid0000-0002-9273-2078-
dc.authorid0000-0001-6646-0358-
dc.departmentİzmir Institute of Technology. Chemical Engineeringen_US
dc.identifier.volume28en_US
dc.identifier.issue15en_US
dc.identifier.startpage9837en_US
dc.identifier.endpage9855en_US
dc.identifier.wosWOS:000686461000002en_US
dc.identifier.scopus2-s2.0-85112807366en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.identifier.doi10.1007/s10570-021-04148-3-
dc.identifier.wosqualityQ1-
dc.identifier.scopusqualityQ1-
item.languageiso639-1en-
item.grantfulltextopen-
item.fulltextWith Fulltext-
item.cerifentitytypePublications-
item.openairetypeArticle-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
crisitem.author.dept03.02. Department of Chemical Engineering-
crisitem.author.dept03.02. Department of Chemical Engineering-
Appears in Collections:Chemical Engineering / Kimya Mühendisliği
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
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