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https://hdl.handle.net/11147/11816
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DC Field | Value | Language |
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dc.contributor.author | Morimoto, Tsumoru | - |
dc.contributor.author | Wang, Chuang | - |
dc.contributor.author | Tanimoto, Hiroki | - |
dc.contributor.author | Artok, Levent | - |
dc.contributor.author | Kakiuchi, Kiyomi | - |
dc.date.accessioned | 2021-12-02T18:16:15Z | - |
dc.date.available | 2021-12-02T18:16:15Z | - |
dc.date.issued | 2021 | - |
dc.identifier.issn | 0039-7881 | - |
dc.identifier.issn | 1437-210X | - |
dc.identifier.uri | https://doi.org/10.1055/a-1468-8377 | - |
dc.identifier.uri | https://hdl.handle.net/11147/11816 | - |
dc.description.abstract | The rhodium(I)-catalyzed reaction of alkynes with aryl-boronic acids in the presence of formaldehyde results in a CO-gas-free arylative dual-carbonylation to produce gamma-butenolide derivatives. The simultaneous loading of phosphine-ligated and phosphine-free rhodium(I) complexes is required for efficient catalysis. The former complex catalyzes the abstraction of a carbonyl moiety from formaldehyde through the activation of its formyl C-H bond (decarbonylation) and the latter catalyzes the subsequent dual-incorporation of the resulting carbonyl unit (carbonylation). The use of larger amounts of the phosphine-ligated rhodium(I) complex generates more carbonyl units, leading to the formation gamma-butenolides via the dual-incorporation of the carbonyl unit. | en_US |
dc.language.iso | en | en_US |
dc.publisher | Georg Thieme Verlag | en_US |
dc.relation.ispartof | Synthesis | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | C-H activation | en_US |
dc.subject | Decarbonylation | en_US |
dc.subject | Rhodium | en_US |
dc.subject | Formaldehyde | en_US |
dc.subject | Gamma-butenolides | en_US |
dc.subject | Alkynes | en_US |
dc.subject | Arylboronic acids | en_US |
dc.title | Rhodium(I)-catalyzed CO-gas-free arylative dual-carbonylation of alkynes with arylboronic acids via the formyl C-H activation of formaldehyde | en_US |
dc.type | Article | en_US |
dc.institutionauthor | Artok, Levent | - |
dc.department | İzmir Institute of Technology. Chemistry | en_US |
dc.identifier.volume | 53 | en_US |
dc.identifier.issue | 18 | en_US |
dc.identifier.startpage | 3372 | en_US |
dc.identifier.endpage | 3382 | en_US |
dc.identifier.wos | WOS:000642292100001 | en_US |
dc.identifier.scopus | 2-s2.0-85104947445 | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.identifier.doi | 10.1055/a-1468-8377 | - |
dc.identifier.wosquality | Q2 | - |
dc.identifier.scopusquality | Q1 | - |
item.grantfulltext | open | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.cerifentitytype | Publications | - |
item.openairetype | Article | - |
item.languageiso639-1 | en | - |
item.fulltext | With Fulltext | - |
crisitem.author.dept | 04.01. Department of Chemistry | - |
Appears in Collections: | Chemistry / Kimya Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection |
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File | Size | Format | |
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morimoto2021.pdf | 476.38 kB | Adobe PDF | View/Open |
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