Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/13601
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dc.contributor.authorBüyükçakır, Onur-
dc.contributor.authorYüksel, Recep-
dc.contributor.authorBegar, Ferit-
dc.contributor.authorErdoğmuş, Mustafa-
dc.contributor.authorArsakay, Madi-
dc.contributor.authorLee, Sun Hwa-
dc.contributor.authorKim, Sang Ouk-
dc.date.accessioned2023-07-27T19:49:58Z-
dc.date.available2023-07-27T19:49:58Z-
dc.date.issued2023-
dc.identifier.issn2574-0962-
dc.identifier.urihttps://doi.org/10.1021/acsaem.3c01163-
dc.identifier.urihttps://hdl.handle.net/11147/13601-
dc.description.abstractWe synthesized and studied a redox-active quinone-basedporousorganic polymer (rPOP) and found ultralong cycle life: it is a promisingorganic cathode for aqueous zinc-ion batteries (ZIBs). It has highphysicochemical stability and enhanced intrinsic conductivity fromits fused-aromatic conjugated skeleton. rPOP's high porosityallows for efficient Zn2+ infiltration through the poresduring charging-discharging cycles and contributes to the efficientutilization of redox-active quinone units. It delivers a specificcapacity of 120 mAh g(-1) at a current density of0.1 A g(-1) with a flat and long discharge plateau,which is critically important to provide a stable voltage output.It provides ultralong cycle life at a current density of 1.0 A g(-1) for 1000 and at 2.0 A g(-1) for 30 000cycles, with initial capacity retention of 95 and 66%, respectively.The co-insertion (Zn2+ and H+) charge storagemechanism was investigated using various electrochemical measurementsand ex/in situ structural characterization techniques, and is explainedherein. These findings contribute to a better understanding of thestructure-property relationship for rPOP and open a new avenuefor new organic cathode materials for high-performance next-generationaqueous batteries.en_US
dc.description.sponsorshipThis work was supported by the IBS (IBS-R019-D1), and subsequently by The Scientific and Technological Research Council of Turkey, TUBITAK Project (220Z024). The authors thank the Nuclear Magnetic Resonance Application and Research Center (NMRM-IZTECH) for the NMR experiments.en_US
dc.language.isoenen_US
dc.publisherAmerican Chemical Societyen_US
dc.relation.ispartofACS Applied Energy Materialsen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectPorous organic polymersen_US
dc.subjectZinc-ion batteriesen_US
dc.subjectOrganic cathodeen_US
dc.subjectEnergy storageen_US
dc.titleUltralong-life quinone-based porous organic polymer cathode for high-performance aqueous zinc-ion batteriesen_US
dc.typeArticleen_US
dc.authorid0000-0003-4626-8232-
dc.institutionauthorBüyükçakır, Onurtr
dc.departmentİzmir Institute of Technology. Chemistryen_US
dc.identifier.wosWOS:001019006000001en_US
dc.identifier.scopus2-s2.0-85164907795en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıtr
dc.identifier.doi10.1021/acsaem.3c01163-
dc.identifier.scopusqualityQ1-
item.cerifentitytypePublications-
item.fulltextWith Fulltext-
item.grantfulltextopen-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.languageiso639-1en-
item.openairetypeArticle-
crisitem.author.dept04.01. Department of Chemistry-
Appears in Collections:Chemistry / Kimya
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
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