Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/14129
Full metadata record
DC FieldValueLanguage
dc.contributor.authorDurgut, Enes-
dc.contributor.authorZhou, Muchu-
dc.contributor.authorDikici, Betuel Aldemir-
dc.contributor.authorFoudazi, Reza-
dc.contributor.authorClaeyssens, Frederik-
dc.date.accessioned2024-01-06T07:21:27Z-
dc.date.available2024-01-06T07:21:27Z-
dc.date.issued2024-
dc.identifier.issn0927-7757-
dc.identifier.issn1873-4359-
dc.identifier.urihttps://doi.org/10.1016/j.colsurfa.2023.132629-
dc.descriptionFoudazi, Reza/0000-0001-6711-3390; Claeyssens, Frederik/0000-0002-1030-939X; Aldemir Dikici, Betul/0000-0002-5516-469X; Durgut, Enes/0000-0002-2224-7325en_US
dc.description.abstractThis study investigates the use of submicron polymeric particles with varying crosslinking densities as the sole stabilizer for producing Polymerized High Internal Phase Emulsions (PolyHIPE). We establish a direct correlation between the crosslinking density and the hydrophilicity of the polymer particles. The hydrophilicity of these particles significantly influences the morphology and rheology of HIPEs. These differences manifest as various morphological variations in the resulting PolyHIPE templates. It was discovered that by increasing the crosslinker weight percentage in the particles from 0 % to 100 %, PolyHIPEs with semi-open, open, and closed porous structures can be obtained. Furthermore, non-crosslinked particles were observed to dissolve in the continuous phase, acting as macromolecular surfactants that generate small pores akin to surfactant-stabilized structures in PolyHIPE. These findings offer fresh insights into the relationship between particle localization at the interface, HIPE rheology, and the formation of pore throats in Pickering PolyHIPEs, leading to the creation of either closed or open porous networks. Additionally, interfacial rheological results demonstrate that particles synthesized with varying monomer-to-crosslinker ratios exhibit different interfacial elasticities, which are linked to PolyHIPE morphology.en_US
dc.description.sponsorshipThe authors gratefully acknowledge the Republic of Turkey-The Ministry of National Education for funding Enes Durgut. They also acknowledge the Engineering and Physical Sciences Research Council (Grant No. EP/I007695/1) and the Medical Research Council (Grant No. MR/L012669/1) for funding the equipment used in this study. Frederik Claeyssens also thanks the Royal Society for funding of a Royal Society Leverhulme Trust Senior Research Fellowship 2022 (SRF\R1\221053) . We also acknowledge Dr. Christopher Holland for conducting bulk rheological measurements.en_US
dc.description.sponsorshipRepublic of Turkey-The Ministry of National Education; Engineering and Physical Sciences Research Council [SRF\R1\221053]; Medical Research Council [MR/L012669/1]; Royal Society; [EP/I007695/1]en_US
dc.description.sponsorshipThe authors gratefully acknowledge the Republic of Turkey-The Ministry of National Education for funding Enes Durgut. They also acknowledge the Engineering and Physical Sciences Research Council (Grant No. EP/I007695/1) and the Medical Research Council (Grant No. MR/L012669/1) for funding the equipment used in this study. Frederik Claeyssens also thanks the Royal Society for funding of a Royal Society Leverhulme Trust Senior Research Fellowship 2022 (SRF\R1\221053) . We also acknowledge Dr. Christopher Holland for conducting bulk rheological measurements.en_US
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofColloids and Surfaces A-Physicochemical and Engineering Aspectsen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectPickering emulsionsen_US
dc.subjectRheologyen_US
dc.subjectArrested coalescenceen_US
dc.subjectParticlesen_US
dc.subjectHIPEen_US
dc.subjectPolyHIPEen_US
dc.titleModifying Pickering Polymerized High Internal Phase Emulsion Morphology by Adjusting Particle Hydrophilicityen_US
dc.typeArticleen_US
dc.authorid0000-0002-5516-469X-
dc.authoridFoudazi, Reza/0000-0001-6711-3390-
dc.authoridClaeyssens, Frederik/0000-0002-1030-939X-
dc.authoridAldemir Dikici, Betul/0000-0002-5516-469X-
dc.authoridDurgut, Enes/0000-0002-2224-7325-
dc.institutionauthorAldemir Dikici, Betül-
dc.departmentIzmir Institute of Technologyen_US
dc.identifier.volume680en_US
dc.identifier.wosWOS:001106277900001en_US
dc.identifier.wosWOS:001106277900001-
dc.identifier.scopus2-s2.0-85175560000en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.identifier.doi10.1016/j.colsurfa.2023.132629-
dc.authorscopusid57875239600-
dc.authorscopusid57208746761-
dc.authorscopusid58678256700-
dc.authorscopusid23975458100-
dc.authorscopusid55987061100-
dc.authorwosidDikici, Betül/AAY-9253-2020-
dc.authorwosidFoudazi, Reza/KHD-9949-2024-
dc.authorwosidClaeyssens, Frederik/E-4781-2011-
dc.authorwosidDurgut, Enes/KIA-3031-2024-
dc.identifier.wosqualityQ2-
dc.identifier.scopusqualityQ2-
dc.description.woscitationindexScience Citation Index Expanded-
item.fulltextWith Fulltext-
item.openairetypeArticle-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.languageiso639-1en-
item.cerifentitytypePublications-
item.grantfulltextembargo_20250101-
Appears in Collections:Bioengineering / Biyomühendislik
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
Files in This Item:
File SizeFormat 
1-s2.0-S0927775723017132-main.pdf
  Until 2025-01-01
6.81 MBAdobe PDFView/Open    Request a copy
Show simple item record



CORE Recommender

SCOPUSTM   
Citations

6
checked on Dec 7, 2024

WEB OF SCIENCETM
Citations

5
checked on Nov 9, 2024

Page view(s)

188
checked on Dec 9, 2024

Google ScholarTM

Check




Altmetric


Items in GCRIS Repository are protected by copyright, with all rights reserved, unless otherwise indicated.