Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/14252
Title: Light-Induced Synthesis of Single-Crystalline Gold Microplates in an Open System
Authors: Akkuş, Betül
Mert Balcı, Fadime
Keywords: Nanoparticles
Nanobelts
Growth
Size
Publisher: Amer Chemical Soc
Abstract: Bottom-up synthesis of large single-crystalline gold microplates is of key importance to catalysis, nanophotonics, bioengineering, and plasmonics. However, easy, low-cost, room-temperature, and high-yield synthesis of large gold microplates with several micrometers in lateral size and a few tens of nanometers in thickness by using photochemical synthesis in an open system is still challenging. We herein report on an easy and cost-effective photochemical synthesis of single-crystalline gold microplates with lateral sizes up to around 40 mu m and tens of nanometers in thickness in a few hours of reaction time in an open system containing a lyotropic liquid crystal, which is formed by self-assembly of 10-lauryl ether in a strong acid, sulfuric acid, along with water. We have found that by changing the reaction parameters, such as the reaction time, the concentration of gold ions in the liquid crystal, etc., the thickness and size of the microplates can be easily controlled. Most importantly, the liquid crystalline phase is completely preserved after completion of the photochemical reaction. The microplates can be easily isolated and transferred to different media such as alcohol and water for further studies, or they can be immediately used on a substrate after completion of the reaction. The results obtained in this study will allow us to understand the growth mechanism of gold microplates in open systems, and they will find applications in a variety of critical areas, such as plasmonics, nanophotonics, and catalysis.
URI: https://doi.org/10.1021/acs.jpcc.3c06255
https://hdl.handle.net/11147/14252
ISSN: 1932-7447
1932-7455
Appears in Collections:Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

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