Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/1899
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dc.contributor.authorTüzüner, Şeyda-
dc.contributor.authorDemir, Mustafa Muammer.-
dc.date.accessioned2016-07-14T07:24:00Z
dc.date.available2016-07-14T07:24:00Z
dc.date.issued2015-07
dc.identifier.citationTüzüner, Ş., and Demir, M. M. (2015). Dispersion of organophilic Ag nanoparticles in PS-PMMA blends. Materials Chemistry and Physics, 162, 692-699. doi:10.1016/j.matchemphys.2015.06.044en_US
dc.identifier.issn0254-0584
dc.identifier.issn0254-0584-
dc.identifier.issn1879-3312-
dc.identifier.urihttp://doi.org/10.1016/j.matchemphys.2015.06.044
dc.identifier.urihttp://hdl.handle.net/11147/1899
dc.description.abstractAbstract The preparation of stable composites with well-controlled particle location is one of the challenges in formulating new polymer/nanoparticle mixtures. In this study, cetyltriammonium bromide (CTAB)-capped monodisperse Ag nanoparticles were prepared and mixed with an equimass blend of polystyrene (PS) and poly(methyl methacrylate) (PMMA) in solution. The surface of the blend film without nanoparticles showed spherical pits with a size of 4.5 μm in diameter. The integration of CTAB-capped nanoparticles into the blend film developed surface bumps with a size of 0.4 μm in diameter. The organophilic Ag nanoparticles were distributed heterogeneously in the immiscible PS-PMMA blend. When the diameter of particle domains reached approximately 20 nm, particles were preferentially located at the interface of the PS and PMMA domains. Larger particle domains with a diameter of 90 nm were found to be in the PMMA-rich phase. Isothermal post-treatment of the PS-PMMA/Ag composite films directs the particle domains into PS domains. Thermodynamic factors that contribute to the observed morphologies are discussed.en_US
dc.description.sponsorshipTurkish Academy of Sciences (TÜBA-GEB_IP 2013)en_US
dc.language.isoenen_US
dc.publisherElsevier Ltd.en_US
dc.relation.ispartofMaterials Chemistry and Physicsen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectHeterostructuresen_US
dc.subjectInterfacesen_US
dc.subjectPolymersen_US
dc.subjectSurface propertiesen_US
dc.subjectSilveren_US
dc.titleDispersion of organophilic Ag nanoparticles in PS-PMMA blendsen_US
dc.typeArticleen_US
dc.authoridTR130614en_US
dc.institutionauthorTüzüner, Şeyda-
dc.institutionauthorDemir, Mustafa Muammer-
dc.departmentİzmir Institute of Technology. Materials Science and Engineeringen_US
dc.identifier.volume162en_US
dc.identifier.startpage692en_US
dc.identifier.endpage699en_US
dc.identifier.wosWOS:000359958800088en_US
dc.identifier.scopus2-s2.0-84938739255en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.identifier.doi10.1016/j.matchemphys.2015.06.044-
dc.relation.doi10.1016/j.matchemphys.2015.06.044en_US
dc.coverage.doi10.1016/j.matchemphys.2015.06.044en_US
dc.identifier.wosqualityQ2-
dc.identifier.scopusqualityQ2-
item.languageiso639-1en-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.grantfulltextopen-
item.cerifentitytypePublications-
item.fulltextWith Fulltext-
item.openairetypeArticle-
Appears in Collections:Materials Science and Engineering / Malzeme Bilimi ve Mühendisliği
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
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