Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/2001
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dc.contributor.authorSözüer, Hikmet Işıl-
dc.contributor.authorGünyar, Alev-
dc.contributor.authorDülger İrdem, Seçkiner-
dc.contributor.authorBaya, Miguel-
dc.contributor.authorPoli, Rinaldo-
dc.date.accessioned2016-07-27T13:53:05Z
dc.date.available2016-07-27T13:53:05Z
dc.date.issued2005-08
dc.identifier.citationSözüer, H. I., Günyar, A., Dülger İrdem, S., Baya, M., and Poli, R. (2005). Synthesis, characterization and electrochemical behavior of oxo-bridged (arylimido)[tris(3,5-dimethylpyrazolyl)borato] molybdenum(V) complexes. Inorganica Chimica Acta, 358(12), 3303-3310. doi:10.1016/j.ica.2005.05.018en_US
dc.identifier.issn0020-1693
dc.identifier.issn0020-1693-
dc.identifier.issn1873-3255-
dc.identifier.urihttp://doi.org/10.1016/j.ica.2005.05.018
dc.identifier.urihttp://hdl.handle.net/11147/2001
dc.description.abstractLocate full-text(opens in a new window)|Full Text(opens in a new window)|View at Publisher| Export | Download | Add to List | More... Inorganica Chimica Acta Volume 358, Issue 12, 1 August 2005, Pages 3303-3310 Synthesis, characterization and electrochemical behavior of oxo-bridged (arylimido)[tris(3,5-dimethylpyrazolyl)borato] molybdenum(V) complexes (Article) Topaloglu-Sozuer, I.a , Gunyar, A.a, Dulger-Irdem, S.a, Baya, M.b, Poli, R.b a Department of Chemistry, Faculty of Science, Izmir Institute of Technology, Gulbahce, Urla-35430, Izmir, Turkey b Laboratoire de Chimie de Coordination, UPR CNRS 8241, 205 Route de Narbonne, 31077 Toulouse Cedex, France View references (34) Abstract Reaction of the oxo-molybdenum(V) precursor [MoTp*(O)Cl2] [Tp* = hydrotris(3,5-dimethyl-1-pyrazolyl)borate] with H 2NC6H4R-4 (R = OEt; OPr) in refluxing toluene in the presence of Et3N afforded the binuclear oxo-bridged oxo(arylimido) molybdenum(V) complexes [Tp*Mo(O)Cl](μ-O) [Tp*Mo(NC6H4OR-4)Cl]. Surprisingly, a similar reaction between [MoTp*(O)Cl2] and C6H 5NH2 yielded the previously reported compound [{MoTp*(O)Cl}2(μ-O)] as the only product. The new compounds were characterized by microanalytical data, mass spectrometry, IR and 1H NMR spectroscopy. Cyclic voltammetric studies of the new compounds, of the previously reported compounds [Tp*Mo(O)Cl](μ-O)[Tp*Mo(NAr)Cl] (Ar = C6H4OMe-4, C6H 4F-3, C6H4Cl-4, C6H4Br-4, and C6H4I-3), and of [{MoTp*(O)Cl} 2(μ-O)] revealed a reversible one-electron oxidation process that is little affected by the nature of the substituent on the aryl group, whereas it is greatly affected by replacement of the imido ligand with an oxo ligand. The [{MoTp*(O)Cl}2(μ-O)] compound also shows a one-electron reduction process.en_US
dc.description.sponsorshipTÜBİTAKen_US
dc.language.isoenen_US
dc.publisherElsevier Ltd.en_US
dc.relation.ispartofInorganica Chimica Actaen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subject(Pyrazol)borato complexesen_US
dc.subjectElectrochemistryen_US
dc.subjectImido complexesen_US
dc.subjectMolybdenum complexesen_US
dc.subjectOxo complexesen_US
dc.subjectOxo-bridged Mo(V) complexesen_US
dc.titleSynthesis, characterization and electrochemical behavior of oxo-bridged (arylimido)[tris(3,5-dimethylpyrazolyl)borato] molybdenum(V) complexesen_US
dc.typeArticleen_US
dc.authoridTR132848en_US
dc.authoridTR162483en_US
dc.institutionauthorSözüer, Hikmet Işıl-
dc.institutionauthorGünyar, Alev-
dc.institutionauthorDülger İrdem, Seçkiner-
dc.departmentİzmir Institute of Technology. Chemistryen_US
dc.identifier.volume358en_US
dc.identifier.issue12en_US
dc.identifier.startpage3303en_US
dc.identifier.endpage3310en_US
dc.identifier.wosWOS:000231437700003en_US
dc.identifier.scopus2-s2.0-21844447357en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.identifier.doi10.1016/j.ica.2005.05.018-
dc.relation.doi10.1016/j.ica.2005.05.018en_US
dc.coverage.doi10.1016/j.ica.2005.05.018en_US
dc.identifier.wosqualityQ2-
dc.identifier.scopusqualityQ1-
item.openairetypeArticle-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.fulltextWith Fulltext-
item.languageiso639-1en-
item.cerifentitytypePublications-
item.grantfulltextopen-
crisitem.author.dept04.01. Department of Chemistry-
Appears in Collections:Chemistry / Kimya
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
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