Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/2119
Full metadata record
DC FieldValueLanguage
dc.contributor.authorAksın, Özge-
dc.contributor.authorTürkmen, Hayati-
dc.contributor.authorArtok, Levent-
dc.contributor.authorÇetinkaya, Bekir-
dc.contributor.authorNi, Chaoying-
dc.contributor.authorBüyükgüngör, Orhan-
dc.contributor.authorÖzkal, Erhan-
dc.date.accessioned2016-08-16T10:46:57Z
dc.date.available2016-08-16T10:46:57Z
dc.date.issued2006-06
dc.identifier.citationAksın, O., Türkmen, H., Artok, L., Çetinkaya, B., Ni, C., Büyükgüngör, O., and Özkal, E. (2006). Effect of immobilization on catalytic characteristics of saturated Pd-N-heterocyclic carbenes in Mizoroki-Heck reactions. Journal of Organometallic Chemistry, 691(13), 3027-3036. doi:10.1016/j.jorganchem.2006.03.012en_US
dc.identifier.issn0022-328X
dc.identifier.issn0022-328X-
dc.identifier.uri10.1016/j.jorganchem.2006.03.012
dc.identifier.urihttp://hdl.handle.net/11147/2119
dc.description.abstractA saturated Pd-N-heterocyclic complex was immobilized on an amorphous silica. The complex itself is of very high thermal stability. However, TEM observations, hot filtration, reusability, and poisoning tests all revealed that the complex acted only as a precatalyst to highly active Pd species in Mizoroki-Heck reactions when immobilized. The complex appears more stable when used under homogeneous reaction conditions. The immobilized complex afforded high turnover numbers, 104-105. The higher turnover frequencies were realized at the lower Pd concentrations, which is a characteristic property of ligand-free Pd catalyzed reactions.en_US
dc.description.sponsorshipScientific and Technical Research Council of Turkey (TBAG-2311-103T051), IZTECH (2002-IYTE-36 and 2005-IYTE-18) and Ege University (03/BIL/015)en_US
dc.language.isoenen_US
dc.publisherElsevier Ltd.en_US
dc.relation.ispartofJournal of Organometallic Chemistryen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectC-C couplingen_US
dc.subjectHeterocyclic carbeneen_US
dc.subjectHeterogeneous catalysten_US
dc.subjectImmobilized palladiumen_US
dc.subjectMizoroki-Heck reactionen_US
dc.subjectPalladium leachingen_US
dc.subjectOrganometallicsen_US
dc.titleEffect of immobilization on catalytic characteristics of saturated Pd-N-heterocyclic carbenes in Mizoroki-Heck reactionsen_US
dc.typeArticleen_US
dc.authoridTR1860en_US
dc.institutionauthorAksın, Özge-
dc.institutionauthorArtok, Levent-
dc.institutionauthorÖzkal, Erhan-
dc.departmentİzmir Institute of Technology. Chemistryen_US
dc.identifier.volume691en_US
dc.identifier.issue13en_US
dc.identifier.startpage3027en_US
dc.identifier.endpage3036en_US
dc.identifier.wosWOS:000238309200019en_US
dc.identifier.scopus2-s2.0-33747421306en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.identifier.doi10.1016/j.jorganchem.2006.03.012-
dc.relation.doi10.1016/j.jorganchem.2006.03.012en_US
dc.coverage.doi10.1016/j.jorganchem.2006.03.012en_US
dc.identifier.wosqualityQ2-
dc.identifier.scopusqualityQ1-
dc.identifier.wosqualityttpTop10%en_US
item.fulltextWith Fulltext-
item.grantfulltextopen-
item.openairetypeArticle-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.languageiso639-1en-
item.cerifentitytypePublications-
crisitem.author.dept04.01. Department of Chemistry-
Appears in Collections:Chemistry / Kimya
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
Files in This Item:
File Description SizeFormat 
2119.pdfMakale596.83 kBAdobe PDFThumbnail
View/Open
Show simple item record



CORE Recommender

SCOPUSTM   
Citations

87
checked on Mar 29, 2024

WEB OF SCIENCETM
Citations

85
checked on Apr 26, 2024

Page view(s)

204
checked on Apr 29, 2024

Download(s)

286
checked on Apr 29, 2024

Google ScholarTM

Check




Altmetric


Items in GCRIS Repository are protected by copyright, with all rights reserved, unless otherwise indicated.