Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/2354
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dc.contributor.authorKuş, Melih-
dc.contributor.authorAksın Artok, Özge-
dc.contributor.authorZiyanak, Fırat-
dc.contributor.authorArtok, Levent-
dc.date.accessioned2016-10-31T13:56:20Z-
dc.date.available2016-10-31T13:56:20Z-
dc.date.issued2008-10-
dc.identifier.citationKuş, M., Aksın Artok, Ö., Ziyanak, F., and Artok, L. (2008). Synthesis of α,β-unsaturated ketones by rhodium-catalyzed carbonylative arylation of internal alkynes with arylboronic acids. Synlett, (17), 2587-2592.en_US
dc.identifier.issn0936-5214-
dc.identifier.issn0936-5214-
dc.identifier.urihttp://hdl.handle.net/11147/2354-
dc.identifier.urihttp://doi.org/10.1055/s-2008-1078047-
dc.description.abstractThe Rh-catalyzed reaction of arylboronic acids with internal alkynes under a CO atmosphere in the presence of an acid additive afforded α,β-unsaturated ketones as the major products. Hydroacylation of internal alkynes, except in the case of diaryl acetylenes, proceeded in syn fashion, yielding the E-configured isomer. A mixture of E- and Z-isomers was obtained with diphenyl acetylene. Reactions were also highly regioselective for various nonsymmetric alkynes.en_US
dc.description.sponsorshipScientific and Technical Research Council of Turkey (TBAG-106T385), National Boron Research Institute (BOREN-2006-14-Ç13-09), and IZTECH (2007-IYTE-14)en_US
dc.language.isoenen_US
dc.publisherGeorg Thieme Verlagen_US
dc.relation.ispartofSynletten_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectAlkynesen_US
dc.subjectBoronen_US
dc.subjectCarbonylationen_US
dc.subjectEnonesen_US
dc.subjectRhodiumen_US
dc.titleSynthesis of α,β-unsaturated ketones by rhodium-catalyzed carbonylative arylation of internal alkynes with arylboronic acidsen_US
dc.typeArticleen_US
dc.institutionauthorKuş, Melih-
dc.institutionauthorAksın Artok, Özge-
dc.institutionauthorZiyanak, Fırat-
dc.institutionauthorArtok, Levent-
dc.departmentIzmir Institute of Technology. Chemistryen_US
dc.identifier.issue17en_US
dc.identifier.startpage2587en_US
dc.identifier.endpage2592en_US
dc.identifier.wosWOS:000260777600005en_US
dc.identifier.scopus2-s2.0-55549108402en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.identifier.doi10.1055/s-2008-1078047-
dc.relation.doi10.1055/s-2008-1078047en_US
dc.coverage.doi10.1055/s-2008-1078047en_US
dc.identifier.scopusqualityQ1-
item.fulltextWith Fulltext-
item.openairetypeArticle-
item.cerifentitytypePublications-
item.languageiso639-1en-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.grantfulltextopen-
crisitem.author.dept04.01. Department of Chemistry-
crisitem.author.dept04.01. Department of Chemistry-
Appears in Collections:Chemistry / Kimya
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
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