Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/2460
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dc.contributor.authorKılıçkaya, Gülşah-
dc.contributor.authorDoğan, Başak-
dc.contributor.authorAcar, Nursel-
dc.contributor.authorSözüer, Hikmet Işıl-
dc.date.accessioned2016-11-17T07:58:10Z
dc.date.available2016-11-17T07:58:10Z
dc.date.issued2009-10
dc.identifier.citationKılıçkaya, G., Doğan, B., Acar, N., and Sözüer, H. I. (2009). Reactions of the solvent-stabilized compound [MoOCl2(THF)2] with aromatic nitrogen donor ligands: Spectroscopic characterization and semiempirical AM1* calculations. Turkish Journal of Chemistry, 33(5), 693-708. doi:10.3906/kim-0812-73en_US
dc.identifier.issn1300-0527
dc.identifier.issn1300-0527-
dc.identifier.issn1303-6130-
dc.identifier.urihttp://doi.org/10.3906/kim-0812-73-
dc.identifier.urihttp://hdl.handle.net/11147/2460-
dc.identifier.urihttps://search.trdizin.gov.tr/yayin/detay/92590-
dc.description.abstractReaction of the solvent-stabilized dioxo-molybdenum(VI) compound [MoO2 Cl2 (THF)2]withP Ph3 yielded the oxomolybdenum(IV) species [MoOCl2 (THF)2](1) by the removal of one oxygen atom as PPh3 O. The complexes [MoOCl2 (=NC6 H4 CN)] 2,[MoOCl2 (CNC6 H4 OH)] 3,[MoOCl2 (=NC6 H4 NH2)] 4,and [MoOCl2 (=NC6 H4 OCH3)] 5, were synthesized by the reactions of [MoOCl2 (THF)2]with XC6 H4 Y(X =NH2, Y = CN; X= CN, Y = OH; X = Y = NH2;X=NH2,Y=OCH3). All the new compounds were characterized by elemental analyses, and FTIR, UV-Vis, and 1 H and 13 C-NMR spectra. Geometrical parameters and molecular orbital calculations showed that compounds 2-5 are stabilized by a charge transfer between the Mo center and the phenyl ring.en_US
dc.description.sponsorshipTÜBİTAK (TBAG/2469) and İzmir Institute of Technology (2006 İYTE 15)en_US
dc.language.isoenen_US
dc.publisherTUBITAKen_US
dc.relation.ispartofTurkish Journal of Chemistryen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectMo(VI) complexesen_US
dc.subjectOxo-imido complexesen_US
dc.subjectOxomolybdenum complexesen_US
dc.subjectOxygen atomen_US
dc.titleReactions of the Solvent-Stabilized Compound [moocl2(thf)2] With Aromatic Nitrogen Donor Ligands: Spectroscopic Characterization and Semiempirical Am1* Calculationsen_US
dc.typeArticleen_US
dc.authoridTR132848en_US
dc.institutionauthorKılıçkaya, Gülşah-
dc.institutionauthorDoğan, Başak-
dc.institutionauthorSözüer, Hikmet Işıl-
dc.departmentİzmir Institute of Technology. Chemistryen_US
dc.identifier.volume33en_US
dc.identifier.issue5en_US
dc.identifier.startpage693en_US
dc.identifier.endpage708en_US
dc.identifier.wosWOS:000272356500013en_US
dc.identifier.scopus2-s2.0-77449098925en_US
dc.relation.publicationcategoryMakale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.identifier.doi10.3906/kim-0812-73-
dc.relation.doi10.3906/kim-0812-73en_US
dc.coverage.doi10.3906/kim-0812-73en_US
dc.identifier.trdizinid92590en_US
dc.identifier.wosqualityQ4-
dc.identifier.scopusqualityQ3-
item.fulltextWith Fulltext-
item.openairetypeArticle-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.languageiso639-1en-
item.cerifentitytypePublications-
item.grantfulltextopen-
crisitem.author.dept04.01. Department of Chemistry-
Appears in Collections:Chemistry / Kimya
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
TR Dizin İndeksli Yayınlar / TR Dizin Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
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