Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/3137
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dc.contributor.advisorArtok, Leventen
dc.contributor.authorÜçüncü, Muhammed-
dc.date.accessioned2014-07-22T13:50:57Z-
dc.date.available2014-07-22T13:50:57Z-
dc.date.issued2011en
dc.identifier.urihttp://hdl.handle.net/11147/3137-
dc.descriptionThesis (Master)--İzmir Institute of Technology, Chemistry, İzmir, 2011en
dc.descriptionIncludes bibliographical references (leaves: 60-64)en
dc.descriptionText in English; Abstract: Turkish and Englishen
dc.descriptionxii, 248 leavesen
dc.description.abstractRecently, transition metal catalyzed carbon-carbon bond formation reactions gain numerous importance in organic chemistry. Especially, palladium catalyzed carbon-carbon bond formation reactions provide lots of advantages in organic synthesis. For instance, palladium catalyst is extensively used in many allene formation reactions of various substrates such as propargyl and enyne compounds. This thesis describes the preparation of E-configured aryl or alkenyl functionalized vinylallene structures via the reaction of a 2-en-4-yne carbonates with organoboronic acids in the presence of Pd (0) precursor. This method, which proceeds through formation of s-vinylallenylpalladium intermediate, is applicable for both (E)- and (Z)- configured enyne carbonates and appeared to have wider scope for both organoboronic acids and enyne substrates. The reaction of the carbonate of an enantiomerically enriched enynol reagent with phenylboronic acid under the optimal conditions was proceeded and center-to-axis chirality transfer selectivity was investigated. Complete racemization was observed.en
dc.language.isoenen_US
dc.publisherIzmir Institute of Technologyen
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subject.lcshCarbonatesen
dc.subject.lcshPalladium catalystsen
dc.subject.lcshOrganoboron compoundsen
dc.subject.lcshOrganic acidsen
dc.titlePalladium catalyzed reactions of 2-EN-4-YNE carbonates with organoboronic acidsen_US
dc.typeMaster Thesisen_US
dc.institutionauthorÜçüncü, Muhammed-
dc.departmentThesis (Master)--İzmir Institute of Technology, Chemistryen_US
dc.relation.publicationcategoryTezen_US
item.openairetypeMaster Thesis-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.fulltextWith Fulltext-
item.languageiso639-1en-
item.cerifentitytypePublications-
item.grantfulltextopen-
Appears in Collections:Master Degree / Yüksek Lisans Tezleri
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