Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/4278
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dc.contributor.advisorSofuoğlu, Sait Cemilen_US
dc.contributor.authorYılmaz, Dilek-
dc.date.accessioned2015-05-07T13:43:33Z
dc.date.available2015-05-07T13:43:33Z
dc.date.issued2014
dc.identifier.urihttp://hdl.handle.net/11147/4278
dc.descriptionThesis (Master)--Izmir Institute of Technology, Chemical Engineering, Izmir, 2014en_US
dc.descriptionIncludes bibliographical references (leaves: 47-52)en_US
dc.descriptionText in English; Abstract: Turkish and Englishen_US
dc.descriptionx, 52 leavesen_US
dc.description.abstractA novel sorbent has been developed by immobilizing chitosan onto pumice for As(V) sorption from waters. In order to ensure its functionality, sorption performance was determined by measuring As concentrations in water using hydride generation atomic absorption spectrometry. The success of the immobilization was checked with characterization techniques as scanning electron microscopy, thermal gravimetric analysis, and elemental analysis. Points of zero charges were determined with potentiometric mass titration. Batch type equilibration studies showed that the sorbent can be employed at a wide pH range resulting in quantitative sorption (>90%) at pH 3.0-7.0, and greater than 70% sorption at pH>8.0. These results demonstrate the advantage of immobilizing chitosan onto pumice, because, under the same conditions, pumice displays <20% sorption towards As(V) whereas chitosan gives approximately 90% sorption but only at pH 3.0. The validity of the method was verified through the analysis of ultra-pure, bottled drinking, and tap water samples spiked with arsenate; the respective sorption percentages of 93.2 (±0.7), 89.0 (±1.0), and 80.9 (±1.3) were obtained by batch type equilibration. The sorbent was applied in a column for the spiked samples of ultra-pure and tap water. Similar sorption percentages (60% at the 18th fraction) were obtained for ultra-pure water whereas the methodology gave more efficient results for tap water (90% at the 20th fraction) demonstrating the potential of the sorbent for an efficient water treatment system. Arsenic sorption was also examined in the presence of common interfering ions resulting in competing effects of PO43- and NO3- on As(V) adsorption.en_US
dc.language.isoenen_US
dc.publisherIzmir Institute of Technologyen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectArsenicen_US
dc.subjectChitosanen_US
dc.subjectPumiceen_US
dc.subjectRemovalen_US
dc.subjectBiosorbenten_US
dc.titleDevelopment of a hybrid sorbent composed of natural materials for the removal of arsenic from watersen_US
dc.title.alternativeSulardan arsenik giderimi için doğal malzemelerden yapılmış bir hibrit sorbent geliştirilmesien_US
dc.typeMaster Thesisen_US
dc.institutionauthorYılmaz, Dilek-
dc.departmentIzmir Institute of Technology. Chemical Engineeringen_US
dc.relation.publicationcategoryTezen_US
item.fulltextWith Fulltext-
item.openairetypeMaster Thesis-
item.cerifentitytypePublications-
item.languageiso639-1en-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.grantfulltextopen-
Appears in Collections:Master Degree / Yüksek Lisans Tezleri
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