Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/4527
Title: Preparation of complexes formed in the reaction between dicobaltoctacarbonyl and tetraalkyldiphosphine disulfides, R2P(S)P(S)R2 (R = Me, Et, n-Pr, n-Bu)
Authors: Uğur Sarıkahya, Fadime
Şentürk, Ozan Şanlı
Topaloğlu, Işıl
Keywords: Elemental analyses
Issue Date: 2000
Publisher: Marcel Dekker Inc.
Source: Uğur Sarıkahya, F., Şentürk, O. Ş., and Topaloğlu, I. (2000). Preparation of complexes formed in the reaction between dicobaltoctacarbonyl and tetraalkyldiphosphine disulfides, R2P(S)P(S)R2 (R = Me, Et, n-Pr, n-Bu). Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 30(9), 1697-1702. doi:10.1080/00945710009351862
Abstract: Co2(CO)8 and R2P(S)P(S)R2 (R = Me, Et, n-Pr, n-Bu) react to form the three types of cluster complexes [Co2(μ-CO)(μ4-S)(CO)4]2, (1), [Co4(CO)9(μ3-S)(μ-PR2)2] (2A)-(2D), [(2A), R = Me; (2B), R = Et; (2C), R = n-Pr; (2D), R = n-Bu] and [Co3(CO)7(μ3-S)(SPR2)] (3A)-(3D), [(3A), R = Me; (3B), R = Et; (3C), R = n-Pr; (3D), R = n-Bu]. The structure of (2A) and the disubstituted triphenylphosphine derivative of (3A) were reported previously. The complexes have been characterized by elemental analyses, FT-IR and 31P-[1H] NMR spectroscopy and mass spectrometry.
URI: http://doi.org/10.1080/00945710009351862
http://hdl.handle.net/11147/4527
ISSN: 0094-5714
0094-5714
Appears in Collections:Chemistry / Kimya
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

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