Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/5228
Title: Cleavage of ring A and formation of an unusual nor-triterpene skeleton via the Baeyer-Villiger reaction
Authors: Tağ, Özgür
Çağır, Ali
Khan, Ikhlas A.
Bedir, Erdal
Keywords: 3,5-Seco-4-nor-triterpenes
Baeyer-Villiger
Cycloastragenol
Semi-synthesis
Ring opening
Issue Date: Oct-2012
Publisher: Elsevier Ltd.
Source: Tağ, Ö., Çağır, A., Khan, I. A. and Bedir, E. (2012). Cleavage of ring A and formation of an unusual nor-triterpene skeleton via the Baeyer-Villiger reaction. Tetrahedron Letters, 53(44), 5864-5867. doi:10.1016/j.tetlet.2012.08.068
Abstract: With the aim to generate a compound library for our biological screening studies, cycloastragenol was subjected to chemical transformation studies. The Baeyer-Villiger oxidation experiments provided an interesting 3,5-seco-4-nor-triterpene skeleton via ring opening followed by an unusual rearrangement. A new methodology is described for transforming triterpenoids into 3,5-seco-4-nor derivatives.
URI: http://dx.doi.org/10.1016/j.tetlet.2012.08.068
http://hdl.handle.net/11147/5228
ISSN: 0040-4039
1873-3581
Appears in Collections:Chemistry / Kimya
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

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