Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/5396
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dc.contributor.authorKaragöz, Ezgi Şule-
dc.contributor.authorKuş, Melih-
dc.contributor.authorAkpınar, Gürkan Eray-
dc.contributor.authorArtok, Levent-
dc.date.accessioned2017-04-25T08:59:08Z-
dc.date.available2017-04-25T08:59:08Z-
dc.date.issued2014-10-
dc.identifier.citationKaragöz, E.Ş., Kuş, M., Akpınar, G.E., and Artok, L. (2014). Regio- and stereoselective synthesis of 2,3,5-trienoates by palladium-catalyzed alkoxycarbonylation of conjugated enyne carbonates. Journal of Organic Chemistry, 79(19), 9222-9230. doi:10.1021/jo5014993en_US
dc.identifier.issn0022-3263-
dc.identifier.urihttps://doi.org/10.1021/jo5014993-
dc.identifier.urihttp://hdl.handle.net/11147/5396-
dc.description.abstractPalladium-catalyzed carbonylation of 2,4-enyne carbonates in an alcohol and under balloon pressure of CO proceeds through 1,5-substitution to yield (E)-2,3,5-trienoates. The olefin geometry of the substrate is important to control the overall stereochemistry of this alkoxycarbonylation method. The reaction proceeds through successive formation of π-allylpalladium with an R3 group oriented syn and σ-allenyl palladium complexes.en_US
dc.description.sponsorshipTUBITAKen_US
dc.language.isoenen_US
dc.publisherAmerican Chemical Societyen_US
dc.relation.ispartofJournal of Organic Chemistryen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectCarbonatesen_US
dc.subjectGroup-orienteden_US
dc.subjectStereochemistryen_US
dc.subjectPalladium compoundsen_US
dc.subjectStereoselective synthesisen_US
dc.titleRegio- and stereoselective synthesis of 2,3,5-trienoates by palladium-catalyzed alkoxycarbonylation of conjugated enyne carbonatesen_US
dc.typeArticleen_US
dc.authoridTR1860en_US
dc.institutionauthorKaragöz, Ezgi Şule-
dc.institutionauthorKuş, Melih-
dc.institutionauthorAkpınar, Gürkan Eray-
dc.institutionauthorArtok, Levent-
dc.departmentİzmir Institute of Technology. Chemistryen_US
dc.identifier.volume79en_US
dc.identifier.issue19en_US
dc.identifier.startpage9222en_US
dc.identifier.endpage9230en_US
dc.identifier.wosWOS:000342719600028en_US
dc.identifier.scopus2-s2.0-84907761944en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.identifier.doi10.1021/jo5014993-
dc.identifier.pmid25188027en_US
dc.relation.doi10.1021/jo5014993en_US
dc.coverage.doi10.1021/jo5014993en_US
dc.identifier.wosqualityQ1-
dc.identifier.scopusqualityQ1-
item.languageiso639-1en-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.grantfulltextopen-
item.cerifentitytypePublications-
item.fulltextWith Fulltext-
item.openairetypeArticle-
crisitem.author.dept04.01. Department of Chemistry-
crisitem.author.dept04.01. Department of Chemistry-
Appears in Collections:Chemistry / Kimya
PubMed İndeksli Yayınlar Koleksiyonu / PubMed Indexed Publications Collection
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
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