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https://hdl.handle.net/11147/5396
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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Karagöz, Ezgi Şule | - |
dc.contributor.author | Kuş, Melih | - |
dc.contributor.author | Akpınar, Gürkan Eray | - |
dc.contributor.author | Artok, Levent | - |
dc.date.accessioned | 2017-04-25T08:59:08Z | - |
dc.date.available | 2017-04-25T08:59:08Z | - |
dc.date.issued | 2014-10 | - |
dc.identifier.citation | Karagöz, E.Ş., Kuş, M., Akpınar, G.E., and Artok, L. (2014). Regio- and stereoselective synthesis of 2,3,5-trienoates by palladium-catalyzed alkoxycarbonylation of conjugated enyne carbonates. Journal of Organic Chemistry, 79(19), 9222-9230. doi:10.1021/jo5014993 | en_US |
dc.identifier.issn | 0022-3263 | - |
dc.identifier.uri | https://doi.org/10.1021/jo5014993 | - |
dc.identifier.uri | http://hdl.handle.net/11147/5396 | - |
dc.description.abstract | Palladium-catalyzed carbonylation of 2,4-enyne carbonates in an alcohol and under balloon pressure of CO proceeds through 1,5-substitution to yield (E)-2,3,5-trienoates. The olefin geometry of the substrate is important to control the overall stereochemistry of this alkoxycarbonylation method. The reaction proceeds through successive formation of π-allylpalladium with an R3 group oriented syn and σ-allenyl palladium complexes. | en_US |
dc.description.sponsorship | TUBITAK | en_US |
dc.language.iso | en | en_US |
dc.publisher | American Chemical Society | en_US |
dc.relation.ispartof | Journal of Organic Chemistry | en_US |
dc.rights | info:eu-repo/semantics/openAccess | en_US |
dc.subject | Carbonates | en_US |
dc.subject | Group-oriented | en_US |
dc.subject | Stereochemistry | en_US |
dc.subject | Palladium compounds | en_US |
dc.subject | Stereoselective synthesis | en_US |
dc.title | Regio- and stereoselective synthesis of 2,3,5-trienoates by palladium-catalyzed alkoxycarbonylation of conjugated enyne carbonates | en_US |
dc.type | Article | en_US |
dc.authorid | TR1860 | en_US |
dc.institutionauthor | Karagöz, Ezgi Şule | - |
dc.institutionauthor | Kuş, Melih | - |
dc.institutionauthor | Akpınar, Gürkan Eray | - |
dc.institutionauthor | Artok, Levent | - |
dc.department | İzmir Institute of Technology. Chemistry | en_US |
dc.identifier.volume | 79 | en_US |
dc.identifier.issue | 19 | en_US |
dc.identifier.startpage | 9222 | en_US |
dc.identifier.endpage | 9230 | en_US |
dc.identifier.wos | WOS:000342719600028 | en_US |
dc.identifier.scopus | 2-s2.0-84907761944 | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.identifier.doi | 10.1021/jo5014993 | - |
dc.identifier.pmid | 25188027 | en_US |
dc.relation.doi | 10.1021/jo5014993 | en_US |
dc.coverage.doi | 10.1021/jo5014993 | en_US |
dc.identifier.wosquality | Q1 | - |
dc.identifier.scopusquality | Q2 | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | With Fulltext | - |
item.openairetype | Article | - |
item.languageiso639-1 | en | - |
item.cerifentitytype | Publications | - |
item.grantfulltext | open | - |
crisitem.author.dept | 04.01. Department of Chemistry | - |
crisitem.author.dept | 04.01. Department of Chemistry | - |
Appears in Collections: | Chemistry / Kimya PubMed İndeksli Yayınlar Koleksiyonu / PubMed Indexed Publications Collection Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection |
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