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https://hdl.handle.net/11147/6723
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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Taç, Doğan | - |
dc.contributor.author | Aytaç, İsmet Arınç | - |
dc.contributor.author | Karatavuk, Ali Osman | - |
dc.contributor.author | Kuş, Melih | - |
dc.contributor.author | Ziyanak, Fırat | - |
dc.contributor.author | Artok, Levent | - |
dc.date.accessioned | 2018-01-22T13:45:50Z | - |
dc.date.available | 2018-01-22T13:45:50Z | - |
dc.date.issued | 2017-10 | - |
dc.identifier.citation | Taç, D. , Aytaç, İ. A., Karatavuk, A. O., Kuş, M., Ziyanak, F., and A., L. (2017). Iron-promoted 1,5-substitution (SN2′′) reactions of enyne acetates and oxiranes with Grignard reagents. Asian Journal of Organic Chemistry, 6(10), 1415-1420. doi:10.1002/ajoc.201700225 | en_US |
dc.identifier.issn | 2193-5807 | - |
dc.identifier.uri | http://doi.org/10.1002/ajoc.201700225 | - |
dc.identifier.uri | http://hdl.handle.net/11147/6723 | - |
dc.description.abstract | Acetate derivatives of 2-en-4-yne alcohols 1 and enyne oxiranes 4 regioselectively underwent 1,5-substitution (SN2′′) reactions with Grignard reagents in the presence of an iron compound to provide vinylallenes exclusively with the (E)-configuration. An alkali salt was needed to avoid the hydride-promoted reductive 1,5-substitution pathway for 1, whereas no such additive was needed for the effective conversion of 4 into the desired alkylated or arylated vinylallene structure. | en_US |
dc.description.sponsorship | Scientific and Technological Research Council of Turkey (113Z155) | en_US |
dc.language.iso | en | en_US |
dc.publisher | Wiley | en_US |
dc.relation | 2,4-Enin Oksiranların Grignard Reaktifleri ile Demir ve Bakır Katalizli 1,5-(SN2'')-Sübstitüsyon Tepkimeleri | en_US |
dc.relation.ispartof | Asian Journal of Organic Chemistry | en_US |
dc.rights | info:eu-repo/semantics/openAccess | en_US |
dc.subject | Regioselectivity | en_US |
dc.subject | Nucleophilic substitution | en_US |
dc.subject | Grignard reaction | en_US |
dc.subject | Enynes | en_US |
dc.title | Iron-promoted 1,5-substitution (SN2'') reactions of enyne acetates and oxiranes with Grignard reagents | en_US |
dc.type | Article | en_US |
dc.authorid | 0000-0003-4678-4819 | en_US |
dc.institutionauthor | Taç, Doğan | - |
dc.institutionauthor | Aytaç, İsmet Arınç | - |
dc.institutionauthor | Kuş, Melih | - |
dc.institutionauthor | Ziyanak, Fırat | - |
dc.institutionauthor | Artok, Levent | - |
dc.department | İzmir Institute of Technology. Chemistry | en_US |
dc.identifier.volume | 6 | en_US |
dc.identifier.issue | 10 | en_US |
dc.identifier.startpage | 1415 | en_US |
dc.identifier.endpage | 1420 | en_US |
dc.identifier.wos | WOS:000413355100017 | en_US |
dc.identifier.scopus | 2-s2.0-85025070187 | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.identifier.doi | 10.1002/ajoc.201700225 | - |
dc.relation.doi | 10.1002/ajoc.201700225 | en_US |
dc.coverage.doi | 10.1002/ajoc.201700225 | en_US |
dc.relation.grantno | 113Z155 | - |
dc.identifier.wosquality | Q2 | - |
dc.identifier.scopusquality | Q2 | - |
item.languageiso639-1 | en | - |
item.openairetype | Article | - |
item.grantfulltext | open | - |
item.cerifentitytype | Publications | - |
item.fulltext | With Fulltext | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
crisitem.author.dept | 04.01. Department of Chemistry | - |
crisitem.author.dept | 04.01. Department of Chemistry | - |
crisitem.author.dept | 04.01. Department of Chemistry | - |
Appears in Collections: | Chemistry / Kimya Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection |
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