Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/6723
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dc.contributor.authorTaç, Doğan-
dc.contributor.authorAytaç, İsmet Arınç-
dc.contributor.authorKaratavuk, Ali Osman-
dc.contributor.authorKuş, Melih-
dc.contributor.authorZiyanak, Fırat-
dc.contributor.authorArtok, Levent-
dc.date.accessioned2018-01-22T13:45:50Z-
dc.date.available2018-01-22T13:45:50Z-
dc.date.issued2017-10-
dc.identifier.citationTaç, D. , Aytaç, İ. A., Karatavuk, A. O., Kuş, M., Ziyanak, F., and A., L. (2017). Iron-promoted 1,5-substitution (SN2′′) reactions of enyne acetates and oxiranes with Grignard reagents. Asian Journal of Organic Chemistry, 6(10), 1415-1420. doi:10.1002/ajoc.201700225en_US
dc.identifier.issn2193-5807-
dc.identifier.urihttp://doi.org/10.1002/ajoc.201700225-
dc.identifier.urihttp://hdl.handle.net/11147/6723-
dc.description.abstractAcetate derivatives of 2-en-4-yne alcohols 1 and enyne oxiranes 4 regioselectively underwent 1,5-substitution (SN2′′) reactions with Grignard reagents in the presence of an iron compound to provide vinylallenes exclusively with the (E)-configuration. An alkali salt was needed to avoid the hydride-promoted reductive 1,5-substitution pathway for 1, whereas no such additive was needed for the effective conversion of 4 into the desired alkylated or arylated vinylallene structure.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey (113Z155)en_US
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation2,4-Enin Oksiranların Grignard Reaktifleri ile Demir ve Bakır Katalizli 1,5-(SN2'')-Sübstitüsyon Tepkimelerien_US
dc.relation.ispartofAsian Journal of Organic Chemistryen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectRegioselectivityen_US
dc.subjectNucleophilic substitutionen_US
dc.subjectGrignard reactionen_US
dc.subjectEnynesen_US
dc.titleIron-promoted 1,5-substitution (SN2'') reactions of enyne acetates and oxiranes with Grignard reagentsen_US
dc.typeArticleen_US
dc.authorid0000-0003-4678-4819en_US
dc.institutionauthorTaç, Doğan-
dc.institutionauthorAytaç, İsmet Arınç-
dc.institutionauthorKuş, Melih-
dc.institutionauthorZiyanak, Fırat-
dc.institutionauthorArtok, Levent-
dc.departmentİzmir Institute of Technology. Chemistryen_US
dc.identifier.volume6en_US
dc.identifier.issue10en_US
dc.identifier.startpage1415en_US
dc.identifier.endpage1420en_US
dc.identifier.wosWOS:000413355100017en_US
dc.identifier.scopus2-s2.0-85025070187en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.identifier.doi10.1002/ajoc.201700225-
dc.relation.doi10.1002/ajoc.201700225en_US
dc.coverage.doi10.1002/ajoc.201700225en_US
dc.relation.grantno113Z155-
dc.identifier.wosqualityQ2-
dc.identifier.scopusqualityQ1-
item.grantfulltextopen-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.cerifentitytypePublications-
item.openairetypeArticle-
item.languageiso639-1en-
item.fulltextWith Fulltext-
crisitem.author.dept04.01. Department of Chemistry-
crisitem.author.dept04.01. Department of Chemistry-
crisitem.author.dept04.01. Department of Chemistry-
Appears in Collections:Chemistry / Kimya
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
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