Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/6814
Title: Rhodium(I)-catalyzed carbonylative arylation of alkynes with arylboronic acids using formaldehyde as a carbonyl source
Authors: Wang, Chuang
Morimoto, Tsumoru
Kanashiro, Hiroyuki
Tanimoto, Hiroki
Nishiyama, Yasuhiro
Kakiuchi, Kiyomi
Artok, Levent
Keywords: Alkynes
Arylation
Carbonylation
Formaldehyde
Rhodium
Issue Date: May-2014
Publisher: Georg Thieme Verlag
Source: Wang, C., Morimoto, T., Kanashiro, H., Tanimoto, H., Nishiyama, Y., Kakiuchi, K., and Artok, L. (2014). Rhodium(I)-catalyzed carbonylative arylation of alkynes with arylboronic acids using formaldehyde as a carbonyl source. Synlett, 25(8), 1155-1159. doi:10.1055/s-0033-1341046
Abstract: The rhodium(I)-catalyzed reaction of alkynes with arylboronic acids in the presence of formaldehyde resulted in a carbon monoxide gas-free carbonylative arylation to yield α,β-enones. The simultaneous loading of phosphine-ligated and phosphine-free rhodium(I) complexes is required for efficient catalysis, which catalyze the abstraction of a carbonyl moiety from formaldehyde (decarbonylation) and its subsequent introduction into the substrate (carbonylation), respectively.
URI: http://doi.org/10.1055/s-0033-1341046
http://hdl.handle.net/11147/6814
ISSN: 0936-5214
Appears in Collections:Chemistry / Kimya
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

Files in This Item:
File Description SizeFormat 
6814.pdfMakale200.37 kBAdobe PDFThumbnail
View/Open
Show full item record

CORE Recommender

SCOPUSTM   
Citations

11
checked on Sep 24, 2022

WEB OF SCIENCETM
Citations

13
checked on Sep 24, 2022

Page view(s)

78
checked on Sep 26, 2022

Download(s)

112
checked on Sep 26, 2022

Google ScholarTM

Check

Altmetric


Items in GCRIS Repository are protected by copyright, with all rights reserved, unless otherwise indicated.