Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/7564
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dc.contributor.authorSotthewes, Kai-
dc.contributor.authorKap, Özlem-
dc.contributor.authorWu, Hairong-
dc.contributor.authorThompson, Damien-
dc.contributor.authorHuskens, Jurriaan-
dc.contributor.authorZandvliet, Harold J. W.-
dc.date.accessioned2020-01-07T08:13:10Z-
dc.date.available2020-01-07T08:13:10Z-
dc.date.issued2018-04en_US
dc.identifier.citationSotthewes, K., Kap, Ö., Wu, H. Thompson, D., Huskens, J., and Zandvliet, H. J. W. (2018). Ordering of air-oxidized decanethiols on Au(111). Journal of Physical Chemistry C, 122(15), 8430-8436. doi:10.1021/acs.jpcc.8b01389en_US
dc.identifier.issn1932-7447-
dc.identifier.issn1932-7447-
dc.identifier.issn1932-7455-
dc.identifier.urihttps://doi.org/10.1021/acs.jpcc.8b01389-
dc.identifier.urihttps://hdl.handle.net/11147/7564-
dc.description.abstractSelf-assembled monolayers (SAMs) of alkanethiols on gold are a commonly used platform for nanotechnology owing to their ease of preparation and high surface coverage. Unfortunately, the gold-sulfur bond is oxidized at ambient conditions which alters the stability and structure of the monolayer. We show using scanning tunneling microscopy and X-ray photoelectron spectroscopy that decanethiolate molecules oxidize into decanesulfonates that organize into a hitherto unknown striped phase. Air-exposed SAMs oxidize, as can be determined by a shift of the S 2p peak and the appearance of O 1s photoelectrons as part of the decanethiol monolayer transforms into a lamellae-like decanesulfonate structure when exposed to air. The herringbone structure of the Au(111) surface is preserved, indicating that the interaction between the molecules and the surface is rather weak as these findings are substantiated by density functional theory calculations.en_US
dc.description.sponsorshipFOM (The Netherlands) 11PR2900; TUBITAK; Science Foundation Ireland (SFI), 2214/A International Doctoral Research Fellowship 15/CDA/3491en_US
dc.language.isoenen_US
dc.publisherAmerican Chemical Societyen_US
dc.relation.ispartofJournal of Physical Chemistry Cen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectSelf assembled monolayersen_US
dc.subjectAu(111)en_US
dc.subjectDensity Functional Theoryen_US
dc.subjectAlkanethiolsen_US
dc.subjectSurface coveragesen_US
dc.titleOrdering of Air-Oxidized Decanethiols on Au(111)en_US
dc.typeArticleen_US
dc.institutionauthorKap, Özlem-
dc.departmentİzmir Institute of Technology. Materials Science and Engineeringen_US
dc.identifier.volume122en_US
dc.identifier.issue15en_US
dc.identifier.startpage8430en_US
dc.identifier.endpage8436en_US
dc.identifier.wosWOS:000430896500044en_US
dc.identifier.scopus2-s2.0-85045673344en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.identifier.doi10.1021/acs.jpcc.8b01389-
dc.identifier.pmid29707099en_US
dc.relation.doi10.1021/acs.jpcc.8b01389en_US
dc.coverage.doi10.1021/acs.jpcc.8b01389en_US
dc.identifier.wosqualityQ2-
dc.identifier.scopusqualityQ2-
item.fulltextWith Fulltext-
item.openairetypeArticle-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.languageiso639-1en-
item.cerifentitytypePublications-
item.grantfulltextopen-
crisitem.author.dept03.09. Department of Materials Science and Engineering-
Appears in Collections:Materials Science and Engineering / Malzeme Bilimi ve Mühendisliği
PubMed İndeksli Yayınlar Koleksiyonu / PubMed Indexed Publications Collection
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
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