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https://hdl.handle.net/11147/7564
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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Sotthewes, Kai | - |
dc.contributor.author | Kap, Özlem | - |
dc.contributor.author | Wu, Hairong | - |
dc.contributor.author | Thompson, Damien | - |
dc.contributor.author | Huskens, Jurriaan | - |
dc.contributor.author | Zandvliet, Harold J. W. | - |
dc.date.accessioned | 2020-01-07T08:13:10Z | - |
dc.date.available | 2020-01-07T08:13:10Z | - |
dc.date.issued | 2018-04 | en_US |
dc.identifier.citation | Sotthewes, K., Kap, Ö., Wu, H. Thompson, D., Huskens, J., and Zandvliet, H. J. W. (2018). Ordering of air-oxidized decanethiols on Au(111). Journal of Physical Chemistry C, 122(15), 8430-8436. doi:10.1021/acs.jpcc.8b01389 | en_US |
dc.identifier.issn | 1932-7447 | - |
dc.identifier.issn | 1932-7447 | - |
dc.identifier.issn | 1932-7455 | - |
dc.identifier.uri | https://doi.org/10.1021/acs.jpcc.8b01389 | - |
dc.identifier.uri | https://hdl.handle.net/11147/7564 | - |
dc.description.abstract | Self-assembled monolayers (SAMs) of alkanethiols on gold are a commonly used platform for nanotechnology owing to their ease of preparation and high surface coverage. Unfortunately, the gold-sulfur bond is oxidized at ambient conditions which alters the stability and structure of the monolayer. We show using scanning tunneling microscopy and X-ray photoelectron spectroscopy that decanethiolate molecules oxidize into decanesulfonates that organize into a hitherto unknown striped phase. Air-exposed SAMs oxidize, as can be determined by a shift of the S 2p peak and the appearance of O 1s photoelectrons as part of the decanethiol monolayer transforms into a lamellae-like decanesulfonate structure when exposed to air. The herringbone structure of the Au(111) surface is preserved, indicating that the interaction between the molecules and the surface is rather weak as these findings are substantiated by density functional theory calculations. | en_US |
dc.description.sponsorship | FOM (The Netherlands) 11PR2900; TUBITAK; Science Foundation Ireland (SFI), 2214/A International Doctoral Research Fellowship 15/CDA/3491 | en_US |
dc.language.iso | en | en_US |
dc.publisher | American Chemical Society | en_US |
dc.relation.ispartof | Journal of Physical Chemistry C | en_US |
dc.rights | info:eu-repo/semantics/openAccess | en_US |
dc.subject | Self assembled monolayers | en_US |
dc.subject | Au(111) | en_US |
dc.subject | Density Functional Theory | en_US |
dc.subject | Alkanethiols | en_US |
dc.subject | Surface coverages | en_US |
dc.title | Ordering of Air-Oxidized Decanethiols on Au(111) | en_US |
dc.type | Article | en_US |
dc.institutionauthor | Kap, Özlem | - |
dc.department | İzmir Institute of Technology. Materials Science and Engineering | en_US |
dc.identifier.volume | 122 | en_US |
dc.identifier.issue | 15 | en_US |
dc.identifier.startpage | 8430 | en_US |
dc.identifier.endpage | 8436 | en_US |
dc.identifier.wos | WOS:000430896500044 | en_US |
dc.identifier.scopus | 2-s2.0-85045673344 | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.identifier.doi | 10.1021/acs.jpcc.8b01389 | - |
dc.identifier.pmid | 29707099 | en_US |
dc.relation.doi | 10.1021/acs.jpcc.8b01389 | en_US |
dc.coverage.doi | 10.1021/acs.jpcc.8b01389 | en_US |
dc.identifier.wosquality | Q2 | - |
dc.identifier.scopusquality | Q2 | - |
item.fulltext | With Fulltext | - |
item.openairetype | Article | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.languageiso639-1 | en | - |
item.cerifentitytype | Publications | - |
item.grantfulltext | open | - |
crisitem.author.dept | 03.09. Department of Materials Science and Engineering | - |
Appears in Collections: | Materials Science and Engineering / Malzeme Bilimi ve Mühendisliği PubMed İndeksli Yayınlar Koleksiyonu / PubMed Indexed Publications Collection Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection |
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File | Description | Size | Format | |
---|---|---|---|---|
acs.jpcc.8b01389.pdf | Makale (Article) | 4.47 MB | Adobe PDF | View/Open |
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