Please use this identifier to cite or link to this item:
|Title:||Redox-responsive release of active payloads from depolymerized nanoparticles||Authors:||Lv, Li-Ping
|Issue Date:||2017||Publisher:||Royal Society of Chemistry||Abstract:||The difference in the reactivity of two monomers, aniline (ANI) and 2,5-dimercapto-1,3,4-thiadiazole (DMcT), was employed to design nanoparticles with completely different nanostructures. The monomers were simultaneously polymerized by tandem oxidative polymerization occurring in the miniemulsion droplets. DMcT is also a corrosion inhibitor and its polymer can be depolymerized by reduction, which avoids the unwanted release of the payload DMcT when the capsules are not activated. The redox-responsive release profile of DMcT from the composite particles is controlled by the morphology of the particles and it was investigated for monolithic, multi-hollow, and yolk-shell structures. These PANI/PDMcT composite particles may find potential application in Li-S batteries or in the self-healing systems for corrosion protection.||URI:||https://doi.org/10.1039/c6ra24796b
|Appears in Collections:||Chemistry / Kimya|
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
Show full item record
Items in GCRIS Repository are protected by copyright, with all rights reserved, unless otherwise indicated.