Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/9510
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dc.contributor.authorGöl, Emre Yusuf-
dc.contributor.authorKarabudak, Engin-
dc.date.accessioned2020-07-25T22:12:44Z-
dc.date.available2020-07-25T22:12:44Z-
dc.date.issued2019-
dc.identifier.issn1570-193X-
dc.identifier.urihttps://doi.org/10.2174/1570193X15666181025110759-
dc.identifier.urihttps://hdl.handle.net/11147/9510-
dc.description.abstractBall-type phthalocyanines are recently synthesized binuclear derivatives of the widely known phthalocyanine molecule. In the ball-type Pc molecule, two cofacially arranged Pc rings have four bridged substituents on the peripheral positions of benzenes. Due to their cofacially arranged phthalocyanine rings and, strong intramolecular and intermolecular interactions, ball-type phthalocyanines have different properties than their parent molecule and these structures have many potential application areas. This review describes three different synthesis methods of ball-type phthalocyanines; synthesis in the solvent, synthesis in solid, and synthesis under microwave irradiation. The synthesis that occurs in the shortest time with the highest yield is the synthesis in the solid phase. General differences between a ball-type phthalocyanine and a monophthalocyanine, such as differences in electronic spectra and effects of cofacial arrangement and central metal atoms, are also discussed. The shape of the Q-bands indicates the differences in electronic spectra. In ball-type Pcs, the Q-bands are broad and have poor resolution. Some potential applications, such as gas sensors, NLO devices, potential usage in photodynamic therapy and artificial photosynthesis of ball-type phthalocyanines are also mentioned. Ball-type Pcs can be used as a sensor for gases such as; CO2, CO, SO2, VOC. A novel water-soluble ball-type Pc may have potential application in PDT. Finally, we consider future prospects of these molecules.en_US
dc.language.isoenen_US
dc.publisherBentham Science Publishersen_US
dc.relation.ispartofMini - Reviews in Organic Chemistryen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectBall-type phthalocyanineen_US
dc.subjectBinuclear moleculesen_US
dc.subjectGas sensoren_US
dc.subjectPDTen_US
dc.subjectIntramolecular interactionsen_US
dc.subjectCofacial conformationsen_US
dc.titleMini-review: "Ball-type phthalocyanines": Similarities and differences from mono phthalocyaninesen_US
dc.typeArticleen_US
dc.institutionauthorGöl, Emre Yusuf-
dc.institutionauthorKarabudak, Engin-
dc.departmentİzmir Institute of Technology. Chemistryen_US
dc.identifier.volume16en_US
dc.identifier.issue5en_US
dc.identifier.startpage410en_US
dc.identifier.endpage421en_US
dc.identifier.wosWOS:000472540200003en_US
dc.identifier.scopus2-s2.0-85071147969en_US
dc.relation.publicationcategoryDiğeren_US
dc.identifier.doi10.2174/1570193X15666181025110759-
dc.relation.doi10.2174/1570193X15666181025110759en_US
dc.coverage.doi10.2174/1570193X15666181025110759en_US
dc.identifier.wosqualityQ3-
dc.identifier.scopusqualityQ4-
item.openairetypeArticle-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.fulltextNo Fulltext-
item.languageiso639-1en-
item.cerifentitytypePublications-
item.grantfulltextnone-
crisitem.author.dept04.01. Department of Chemistry-
Appears in Collections:Chemistry / Kimya
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
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