Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/9604
Title: Green fabrication of lanthanide-doped hydroxide-based phosphors: Y(OH)(3):Eu3+ nanoparticles for white light generation
Authors: Güner, Tuğrul
Kuş, Anılcan
Özcan, Mehmet
Genç, Aziz
Şahin, Hasan
Demir, Mustafa Muammer
Keywords: Green synthesis
Phosphors
White LED
White light generation
Publisher: Beilstein-Institut Zur Forderung der Chemischen Wissenschaften
Abstract: Phosphors can serve as color conversion layers to generate white light with varying optical features, including color rendering index (CRI), high correlated color temperature (CCT), and luminous efficacy. However, they are typically produced under harsh synthesis conditions such as high temperature, high pressure, and/or by employing a large amount of solvent. In this work, a facile, water-based, rapid method has been proposed to fabricate lanthanide-doped hydroxide-based phosphors. In this sense, sub-micrometer-sized Y(OH)(3):Eu3+ particles (as red phosphor) were synthesized in water at ambient conditions in <= 60 min reaction time. The doping ratio was controlled from 2.5-20 mol %. Additionally, first principle calculations were performed on Y(OH)(3):Eu3+ to understand the preferable doping scenario and its optoelectronic properties. As an application, these fabricated red phosphors were integrated into a PDMS/YAG:Ce3+ composite and used to generate white light. The resulting white light showed a remarkable improvement (approximate to 24%) in terms of luminous efficiency, a slight reduction of CCT (from 3900 to 3600 K), and an unchanged CRI (approximate to 60) as the amount of Y(OH)(3):Eu3+ was increased.
URI: https://doi.org/10.3762/bjnano.10.119
https://hdl.handle.net/11147/9604
ISSN: 2190-4286
Appears in Collections:Materials Science and Engineering / Malzeme Bilimi ve Mühendisliği
Photonics / Fotonik
PubMed İndeksli Yayınlar Koleksiyonu / PubMed Indexed Publications Collection
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

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