Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/9754
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dc.contributor.authorPolat, Hürriyet-
dc.contributor.authorCohen, H-
dc.contributor.authorMeyerstein, D-
dc.contributor.authorRusonik, I.-
dc.date.accessioned2021-01-24T18:28:25Z-
dc.date.available2021-01-24T18:28:25Z-
dc.date.issued2003-
dc.identifier.issn1387-7003-
dc.identifier.issn1879-0259-
dc.identifier.urihttps://doi.org/10.1016/S1387-7003(03)00247-8-
dc.identifier.urihttps://hdl.handle.net/9754-
dc.description.abstractAn effort was made to synthesize "carbon-free" metal (Fe-0, Co-0, Ni-0) nano-particles via the reduction of their salts with BH4- in aqueous solutions. Surprisingly it was found that when the synthesis is carried out in the presence of CO2, e.g., in aerated solutions, the CO2 is catalytically reduced by BH(4)(-)on the surface of the metal particles. Carbon-free metals can be prepared by reduction under an inert atmosphere. Thus metal surfaces might have acted as catalysts for CO2 fixation, probably via the initial formation of carbon clusters, in the reductive atmosphere in the prebiotic era. (C) 2003 Elsevier B.V. All rights reserved.en_US
dc.language.isoenen_US
dc.publisherElsevier Ltd.en_US
dc.relation.ispartofInorganic Chemistry Communicationsen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectcarbon dioxideen_US
dc.subjectmetal nano-particlesen_US
dc.subjectreductionen_US
dc.subjectsodium borohydrideen_US
dc.titleReduction of carbon dioxide during the synthesis of metal nano-particles in wateren_US
dc.typeArticleen_US
dc.institutionauthorPolat, Hürriyet-
dc.departmentİzmir Institute of Technology. Chemistryen_US
dc.identifier.volume6en_US
dc.identifier.issue9en_US
dc.identifier.startpage1266en_US
dc.identifier.endpage1268en_US
dc.identifier.wosWOS:000185247500025en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.identifier.doi10.1016/S1387-7003(03)00247-8-
dc.relation.doi10.1016/S1387-7003(03)00247-8en_US
dc.coverage.doi10.1016/S1387-7003(03)00247-8en_US
dc.identifier.wosqualityQ2-
dc.identifier.scopusqualityQ2-
item.grantfulltextopen-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.cerifentitytypePublications-
item.openairetypeArticle-
item.languageiso639-1en-
item.fulltextWith Fulltext-
crisitem.author.dept04.01. Department of Chemistry-
Appears in Collections:Chemistry / Kimya
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
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