Topaloğlu, Işıl04.01. Department of Chemistry04. Faculty of Science01. Izmir Institute of Technology2016-04-142016-04-141996Topaloğlu, I. (1996). Synthesis, characterization and reactivity of [exo-nido-Rh(PPh3)2(η5-C2B 9H10Me2)]. Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 26(8), 1295-1305. doi:10.1080/009457196080051250094-57141532-2440http://doi.org/10.1080/00945719608005125https://hdl.handle.net/11147/4504In this work, the reaction of the 16-electron species [Rh(η3-C8H13)-(η5-C 2B9H9Me2)] with PPh3 was investigated and the product, [exo-nido-Rh-(PPh3)2(η5-C2B 9H10Me2)], which is in an equilibrium with the closo analogue was characterized by 31p{1H}, 1H, 13C and 11B NMR spectroscopy. A mechanism for the complex formation is suggested which is related to the previously reported reactions between the 16-electron complex and PR3 (R = Me and Et) ligands.eninfo:eu-repo/semantics/openAccessSynthesis(Chemistry)Organometallic chemistryArticle2-s2.0-004015574210.1080/0094571960800512510.1080/00945719608005125