Akpınar, G. ErayKuş, MelihÜçüncü, MuhammedKarakuş, ErmanArtok, Levent2017-01-202017-01-202011Akpınar, G. E., Kuş, M., Üçüncü, M., Karakuş, E., and Artok, L. (2011). Palladium-catalyzed alkoxycarbonylation of (Z)-2-En-4-yn carbonates leading to 2,3,5-trienoates. Organic Letters, 13 (4), 748-751. doi:10.1021/ol102989q1523-70601523-70521523-7060http://doi.org/10.1021/ol102989qhttps://hdl.handle.net/11147/2829Pd(0)-catalyzed carbonylation of (Z)-2-en-4-yn carbonates in the presence of a balloon pressure of CO in an alcohol donates vinylallenyl esters with an exclusively E-configuration and in high yields. The fact that no such reactivity could be observed with E-configured enyne carbonates may indicate that the reaction is promoted via the cooperative coordination of palladium with both alkynyl and carbonate moieties.eninfo:eu-repo/semantics/openAccessAlkoxycarbonylationCarbonatesArticle2-s2.0-7995162948810.1021/ol102989q10.1021/ol102989q