Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/13590
Title: Polyoxometalate-based hybrid composites in multi-functional wastewater treatment applications
Authors: Recepoğlu, Yaşar Kemal
Gören, Ayşegül Yağmur
Orooji, Yasin
Vatanpour, Vahid
Kudaibergenov, Nurbolat
Khataee, Alireza
Keywords: Polyoxometalates
Wastewater remediation
Adsorbent
Membrane modification
Photocatalyst
Fenton -like catalyst
Issue Date: 2023
Publisher: Elsevier
Abstract: The inorganic polyanionic clusters known as polyoxometalates (POMs) have several structural variations at the nanoscale scale. They have many uses in chemistry, materials science, medicine, and other fields. This review considers the developments in treating hazardous contaminants from wastewater using POMs-based compounds. Four main treatment methods using POM-based compounds to remove water pollutants have been developed: adsorption, photocatalytic treatment, Fenton-like treatment, and membrane separation. Moreover, we report the types of POMs, synthesis procedures, strategies performed to modify POM-based compounds, and their appli-cations in wastewater treatment. To promote the development of these compounds for large-scale production and real-scale applications, gaps in knowledge and recent research obstacles are also pointed out. Most research on metal organic complexes (MOCs) based on POM has focused on using these compounds as catalysts, with little focus on their additional uses. The adsorption and photocatalytic efficiency of modified POM-based compounds are attributed to their enhanced contaminant removal efficiency, and recovery of certain POM-based compounds by magnetic separation is presented as a promising option for their recyclability. Among the reviewed studies, the highest adsorption capacity was 1108.9 mg/g, with a removal efficiency of 100 % for acid red dye using poly-[N,N-dimethyl-dodecyl-(4-vinylbenzyl)ammonium chloride] (PIL)-POM. The studies also indicate that the POM-based adsorbents could be effectively reused to remove pollutants and sustain their activity in 3-10 cycles. This review is believed to provide an overview of recent advancements in POM-based compounds for water and wastewater treatment, offers thorough research to anyone interested in learning more about this topic, and acts as a manual for researchers working in this area.
URI: https://doi.org/10.1016/j.jwpe.2023.103863
https://hdl.handle.net/11147/13590
ISSN: 2214-7144
Appears in Collections:Chemical Engineering / Kimya Mühendisliği
Environmental Engineering / Çevre Mühendisliği
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

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