Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/9510
Title: Mini-review: "Ball-type phthalocyanines": Similarities and differences from mono phthalocyanines
Authors: Gol, Emre Yusuf
Karabudak, Engin
Keywords: Ball-type phthalocyanine
binuclear molecules
gas sensor
PDT
intramolecular interactions
cofacial conformations
Issue Date: 2019
Publisher: Bentham Science Publishers B.V.
Abstract: Ball-type phthalocyanines are recently synthesized binuclear derivatives of the widely known phthalocyanine molecule. In the ball-type Pc molecule, two cofacially arranged Pc rings have four bridged substituents on the peripheral positions of benzenes. Due to their cofacially arranged phthalocyanine rings and, strong intramolecular and intermolecular interactions, ball-type phthalocyanines have different properties than their parent molecule and these structures have many potential application areas. This review describes three different synthesis methods of ball-type phthalocyanines; synthesis in the solvent, synthesis in solid, and synthesis under microwave irradiation. The synthesis that occurs in the shortest time with the highest yield is the synthesis in the solid phase. General differences between a ball-type phthalocyanine and a monophthalocyanine, such as differences in electronic spectra and effects of cofacial arrangement and central metal atoms, are also discussed. The shape of the Q-bands indicates the differences in electronic spectra. In ball-type Pcs, the Q-bands are broad and have poor resolution. Some potential applications, such as gas sensors, NLO devices, potential usage in photodynamic therapy and artificial photosynthesis of ball-type phthalocyanines are also mentioned. Ball-type Pcs can be used as a sensor for gases such as; CO2, CO, SO2, VOC. A novel water-soluble ball-type Pc may have potential application in PDT. Finally, we consider future prospects of these molecules.
Description: WOS: 000472540200003
URI: https://doi.org/10.2174/1570193X15666181025110759
https://hdl.handle.net/11147/9510
ISSN: 1570-193X
Appears in Collections:Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

Show full item record

CORE Recommender

SCOPUSTM   
Citations

1
checked on Dec 4, 2021

WEB OF SCIENCETM
Citations

2
checked on Dec 4, 2021

Page view(s)

14
checked on Dec 5, 2021

Google ScholarTM

Check

Altmetric


Items in GCRIS Repository are protected by copyright, with all rights reserved, unless otherwise indicated.