Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/4754
Title: Hydrothermal synthesis and characterization of a new layered compound Li2VGeO5
Authors: Eanes, Mehtap
Kolis, Joseph W.
Keywords: Antiferromagnetic coupling
Crystal structure
Hydrothermal method
Lithium compounds
Electronic configuration
Issue Date: May-2004
Publisher: Elsevier Ltd.
Source: Emirdag-Eanes, M., and Kolis, J. W. (2004). Hydrothermal synthesis and characterization of a new layered compound Li2VGeO5. Journal of Alloys and Compounds, 370(1-2), 90-93. doi:10.1016/j.jallcom.2003.09.027
Abstract: The new compound Li2VGeO5 with a layered structure has been synthesized at 580°C via the hydrothermal method. The compound crystallizes in the space group P4/n of the tetragonal system with two formula units in a cell of dimensions a=6.5187(9)Å, c=4.5092(9)Å (T=298K), V=191.61(5)Å3. The structure is composed of layers made of repeating [(VO5)(GeO4)]1- units. Li+ ions reside between the layers. The magnetic susceptibility data show an antiferromagnetic coupling below 5K with C=0.47emuKmol-1, and θ=-13K with μeff=1.89μB for each Li 2VGeO5 unit.
URI: http://doi.org/10.1016/j.jallcom.2003.09.027
http://hdl.handle.net/11147/4754
ISSN: 0925-8388
0925-8388
Appears in Collections:Chemistry / Kimya
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

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