Please use this identifier to cite or link to this item: https://hdl.handle.net/11147/9530
Title: Synthesis and structures of 1,3,2,4,5-diazatriborolidines
Authors: Fırıncı, Erkan
Sevinçek, Resul
Bursalı, Banu
Özgener, Hüseyin
Burgaz, Osman
Şen, Ceren
Şahin, Yüksel
Keywords: Azaborolidine
Diazatriborole
Enthalpy of formation
Heterocyclic
Issue Date: 2019
Publisher: Elsevier
Abstract: The derivatives of diazatriborolidine are a class of 5-membered heterocyclic compounds containing a ring with two nitrogen atoms and three boron atoms. The 1,3,2,4,5-diazatriborolidine derivatives were synthesized from 1,2-bis(N-lithium-arylamino) diborane(4) and dichloro-dimethylaminoborane with high yield. The structures of these new derivatives were determined using nuclear magnetic resonance (NMR) spectroscopy. The molecular structures of 3a, 3b, 3d, 4b and 4c were determined using single-crystal X-ray diffraction. Their structural features were discussed and compared with similar diazatriborolidines. In addition, the enthalpy of formation of B and N atoms containing five membered heterocycles were calculated theoretically for the first time. Also, an easy and efficient synthesis route has been reported for preparation of 1,3,2,4,5-diazatriborolidine derivatives.
URI: https://doi.org/10.1016/j.ica.2019.119038
https://hdl.handle.net/11147/9530
ISSN: 0020-1693
1873-3255
Appears in Collections:Chemistry / Kimya
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

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