Hydrogenation of Citral Over Pt and Pt-Sn Catalysts
| dc.contributor.author | Aykaç, Hilal | |
| dc.contributor.author | Yılmaz, Selahattin | |
| dc.date.accessioned | 2016-10-31T10:43:56Z | |
| dc.date.available | 2016-10-31T10:43:56Z | |
| dc.date.issued | 2008 | |
| dc.description.abstract | Hydrogenation of citral on monometallic (Pt) and bimetallic (Pt-Sn) catalysts was investigated. It was found that the catalyst activities and product distributions were different over Na-Y and Clino supports. Among monometallic catalysts, Pt/Na-Y was more selective to citronellol (3.9%) and unsaturated alcohols, geraniol and nerol, (14.1%). Sn addition increased the catalyst activities. However, its effect on product distribution differed. Yield of geraniol+nerol changed from 5.1% to 19.7% over Clino. However, selectivity to unsaturated alcohols over Na-Y decreased when it was prepared as a bimetallic catalyst support. Unsaturated alcohol formation was favored when there was a metal support interaction over monometallic catalysts, and metal-promoter interaction over bimetallic catalyst. | en_US |
| dc.description.sponsorship | İzmir Institute of Technology grant number 2002-IYTE-14 | en_US |
| dc.identifier.citation | Aykaç, H., and Yılmaz, S. (2008). Hydrogenation of citral over Pt and Pt-Sn catalysts. Turkish Journal of Chemistry, 32(6), 653-662. | en_US |
| dc.identifier.issn | 1300-0527 | |
| dc.identifier.issn | 1303-6130 | |
| dc.identifier.scopus | 2-s2.0-59449105520 | |
| dc.identifier.uri | https://hdl.handle.net/11147/2351 | |
| dc.identifier.uri | https://search.trdizin.gov.tr/yayin/detay/83037 | |
| dc.language.iso | en | en_US |
| dc.publisher | TUBITAK | en_US |
| dc.relation.ispartof | Turkish Journal of Chemistry | en_US |
| dc.rights | info:eu-repo/semantics/openAccess | en_US |
| dc.subject | Citral | en_US |
| dc.subject | Citronellal | en_US |
| dc.subject | Hydrogenation | en_US |
| dc.subject | Unsaturated alcohols | en_US |
| dc.subject | Zeolite catalysts | en_US |
| dc.title | Hydrogenation of Citral Over Pt and Pt-Sn Catalysts | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication | |
| gdc.author.id | ||
| gdc.author.institutional | Aykaç, Hilal | |
| gdc.author.institutional | Yılmaz, Selahattin | |
| gdc.author.institutional | Yılmaz, Selahattin | |
| gdc.author.yokid | 22592 | |
| gdc.coar.access | open access | |
| gdc.coar.type | text::journal::journal article | |
| gdc.description.department | İzmir Institute of Technology. Chemical Engineering | en_US |
| gdc.description.endpage | 662 | en_US |
| gdc.description.issue | 6 | en_US |
| gdc.description.publicationcategory | Makale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| gdc.description.scopusquality | Q3 | |
| gdc.description.startpage | 653 | en_US |
| gdc.description.volume | 32 | en_US |
| gdc.description.wosquality | Q4 | |
| gdc.identifier.trdizinid | 83037 | |
| gdc.identifier.wos | WOS:000262864700001 | |
| gdc.scopus.citedcount | 3 | |
| gdc.wos.citedcount | 2 | |
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